Transport information adr ohs proper shipping name. Method 6700, issue 2, dated 15 january 1998 page 2 of 5 niosh manual of analytical methods nmam, fourth edition reagents. Exposure controls personal protection engineering measures provide natural or mechanical ventilation to prevent oxygen deficient atmospheres below. Most no 2 is emitted by combustion fossil fuels, wildfires. Nitrous oxide n2o is a greenhouse gas with significant anthropogenic sources contributing to its worldwide abundance.
Nitrogen dioxide immediately contact emergency personnel. Identification of the substancemixture and of the companyundertaking 1. Nitrogen dioxide page 3 of 6 on skin contact with nitrogen dioxide, immediately wash or shower to remove the chemical. Emergency responders must wear the proper personal protective equipment suitable for the situation to which they are responding. Mixture of carbon dioxide and nitrogen msds no p180156a date. It does not contain any class i or class ii ozone depleting chemicals 40 cfr part 82. Find the safety data sheets sds for the products you are interested in from the alphabetical listing below. At the end of the workshift, wash any areas of the body that may have contacted nitrogen dioxide, whether or not known skin contact has occurred. Station road, coleshill b46 1jy birmingham united kingdom 01675462424 en english sds ref sds090clp 110 danger. Emergency telephone numbers 800 5239374 continental u. Classically known as a major component of both indoor and outdoor air pollution. Its dimer, nitrogen tetroxide n 2 o 4, is colorless. Nitrogen, compressed safety data sheet p4631 according to u. It is a strongly fuming, colorless, and liquid miscible with water in.
Firefighting measures guards suitable extinguishing media. Nitrogen dioxide no2 cid 3032552 structure, chemical names, physical and. Monkeys exposed to nitrogen dioxide at 10 ppm for 1 month or at 5 ppm for 2 months showed a marked decrease in resistance to infections. Passive dosimeters for nitrogen dioxide in personalindoor air sampling. Nitrogen dioxide is corrosive to copper and its alloys.
Water safety data sheet according to federal register vol. Nitrogen dioxide is used in many applications, primarily in environmental monitoring. Not listed as a marine pollutant by dot 49 cfr part 171. White fuming nitric acid, also called 100% nitric acid or wfna, is very close to anhydrous nitric acid. There are seven oxides of nitrogen that may be found in the ambient air. Acute gas inhale toxicity category 1 corrosive to metal category 1. Nitrogen oxides pollutant removal nox abatement usp. Method 6004, issue 2, dated 15 august 1994 page 2 of 4 reagents. Nitrogen oxides are major pollutants in the atmosphere, being a precursor to acid rain, photochemical smog, and ozone accumulation. Material safety data sheet liquid nitrogen roc group of companies page 5 of 6 mutagenicity. Reactive nitrogen species rns include, nitrogen dioxide.
This material may cause long lasting harmful effects to aquatic life. Do not eat, smoke, or drink where nitrogen dioxide is. In a fire or if heated, a pressure increase will occur and the container may burst or explode. Two of the most toxicologically significant nitrogen oxides are nitric oxide and nitrogen dioxide. Nitrogen dioxide collects on the first tube tube a, and is thereby separated from nitric oxide, which is oxidized by tube b and then is collected on tube c adjacent to the sampling pump. Composition and information on ingredients carbon dioxide 12438. The lung can be exposed to a variety of reactive nitrogen intermediates through the inhalation of environmental oxidants and those produced during inflammation. Determination of nitratenitrite nitrogen by automated.
Nitrogen oxides nox abatement with hydrogen peroxide introduction. This material increases the risk of fire and may aid combustion. Material safety data sheet liquid nitrogen roc group of companies page 1 of 6 1. Sampling and analytical methods nitrogen dioxide in. Msds document numbern000 revision dated 03 sept 96 in an emergency, call chemtrec at 8004249300 us toll free or 7035273887 contents. Nitrogen dioxide no2 and n2o4 safety data sheet sds. The nitrite ion no 2 formed from the above reaction can be analyzed via conventional analytical methods 8. Nitric oxide is extremely toxic by inhalation, and symptoms of overexposure may not become apparent for up. Cool containers with water spray until well after the fire is out. If appropriate, install automatic monitoring equipment to detect the level of nitrogen dioxide, and oxygen. The oxides are mainly nitric oxide nox and nitrogen dioxide no2 both of which are corrosive and hazardous to health.
Cryogenic liquid nitrogen, liquid nitrogen, lin chemical formula. However, nitric oxide no and nitrogen dioxide no2 are the two principal nitrogen oxides associated with combustion sources. Nitrogen oxides nitric oxide, nitrogen dioxide, etc. It is used to produce other chemicals, as a nitrating and oxidizing agent, in. Exposure controls personal protection continued ventilation and engineering controls continued. Nitrogen dioxide is very corrosive to most metals under wet conditions greater 10% water, except stainless steels, particularly with high chromium content, and nickelchromiumiron molybdenum and nickelchromiummolybdenum alloys and aluminum. These procedures were designed and tested for internal use by osha personnel. Pdf passive dosimeters for nitrogen dioxide in personal. Hazards identification danger hazard classification. Reaction with hydrochloric acid may form bischloromethyl ether, an. Nitrogen dioxide is a dark brown to yellowish liquid or reddishbrown gas with a strong odor. In this case, however, the titration is dilutionsensitive and distillate volumes samples and blanks should be. This material safety data sheet msds serves different purposes than and does not. Exposure controlspersonal protection nitrogen dioxide acgih tlv united states, 620.
Product and company identification advanced specialty gases 5 catron dr. Nitrogen msds material safety data sheet for nitrogen n2 reference. Reacts violently with perchloric acid, perchloric acidaniline mixtures, and nitromethane. Ambient concentrations of these two gases vary widely. Physical data are typical values, but may vary from sample to sample. Documentation of the tlvs, 7th section 4 first aid measures eyes. Shipped as a liquefied gas under own vapor pressure.
Method s320, nitrogen dioxide, was evaluated over the range 3. Carbon monoxide, nitrogen oxides, phosphorous oxides. Dinitrogen tetroxide, nitrogen peroxide, nitrogen tetroxide cas number 10102440. You can obtain copies of sampling results from your employer. Nitrogen dioxide disproportionates to nitrite and nitrate ions in the presence of tea. Details of the supplier of the safety data sheet air liquide america specialty gases 6141 easton rd. Nitrogen oxides are a mixture of gases that are composed of nitrogen and oxygen. The high background levels of nitrate found in commercial teaims sorbents ruled out further research to assess this no 2tea disproportionation product by ic. Add 20 ml glycerol and dilute with deionized water to 1 l. Nitrogen 7727379 99 % there are no specific exposure limits for nitrogen. Safety data sheet nitrogen, refrigerated liquid n2 date of first issue. In the presence of air, nitric oxide forms brown fumes of nitrogen dioxide and is extremely reactive and a strong oxidizing agent. Proper shipping name nitrogen, compressed hazard class 2. Nitric oxide is a sharp sweetsmelling gas at room temperature, whereas nitrogen dioxide has a strong.
Material safety data sheet msds section i trade name gas samples, nonpressurized, flammable un3167 chemical name and synonyms methane gas, hydrocarbon gas mixture, natural gas section ii hazardous ingredients methane cas 74828 carbon dioxide cas 124389 nitrogen cas 124389 ethane cas 74840 propane cas 74986 butane cas. Nitrogen dioxide is soluble in water, reddishbrown in colour, and a strong oxidant. Nitrogen dioxide space administration nitrogen dioxideor no 2is a toxic gas found in our atmosphere. Regulatory information international inventories legend u. If nitric oxide is not to be determined, a flow rate of up to 0.
Nitrous oxide, compressed safety data sheet sds p4636. Material safety data sheet product name airgas inc. Nitrogen dioxide academic dictionaries and encyclopedias. Nitrogen dioxide 001041 syntheticanalytical chemistry.
Additionally, nitrogen dioxide in balances of air or nitrogen at various concentrations are used as span gas calibration mixtures for engine emissions testing in the automotive industry and are part 86 compliant. Noncombustible, but accelerates the burning of combustible materials. Federal regulations sara 3 section 3 of title iii of the superfund amendments and reauthorization act of 1986 sara. Nitric acid is a chemical of great commercial importance because of its use in the manufacture of explosives like nitroglycerine, trinitrotoluene, gum cotton nitrocellulose, picric acid, etc. Relevant identified uses of the substance or mixture and uses advised against use of the substancemixture. Nitrogen dioxide appears as a reddish brown gas or yellowishbrown liquid when cooled or compressed.
Safety data sheet air liquide msds document library. Nitrogen is a colorless, odorless, nonflammable gas, or a colorless, odorless, cryogenic liquid. At high temperatures associated with combustion, molecular nitrogen n 2 and oxygen o 2 split into. The more organic waste and moisture present in a landfill, the more landfill gas is produced by the bacteria during decomposition. Nitrogen dioxide in workplace atmospheres ion chromatography pdf disclaimer. Combine 1 part reagent grade triethanolamine tea with 7 parts analytical grade acetone.
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